Thanks to our wonderful monkey in shiny white armour, and Jerseylynn for the great thinking, we now have a function to show the chat moderators online.
I tested it today and it works great!
Pressing the name of the moderator, that show up in the chat room, will open up a new tab with a pm. Just fill out your issue, don't forget to take a screenshot if there's something breaking the site guidelines.
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Also, Gold membership will let you past the 25 person/room limit.
Happy Lushing!